It has been proposed that the platinum fluoride forms a negatively charged polymeric network with xenon or xenon fluoride cations held in its interstices. In vapor phase hydrolysis occurs more smoothly. Platinum is a chemical element with the atomic number 78 in the periodic table. Norman form of the Germanic name Alia, which was a short form of names containing the Germanic element ali meaning 'other'. The required PtF5 can be obtained by fluorinating PtCl2: Platinum hexafluoride can gain an electron to form the hexafluoroplatinate anion, PtF [1], PtF6 was first prepared by reaction of fluorine with platinum metal. See more Chemical formula A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets . Platinum hexafluoride -PtF 6. 13693-05-5 . Platinum Hexafluoride Hexafluoroplatinate Xenon hexafluoroplatinate Xenon PtF6 can also be prepared by disproportionation of the pentafluoride (PtF5), with the tetrafluoride (PtF4) as a byproduct. - Journal of the American Chemical Society. : 100% (1/1) PtF 6 platinum(VI) fluoride. Thus the interaction of XeF/sub 2/ with platinum fluorides (PtF/sub 4/. It is used in research. All are aggressive oxidants. Platinum(VI) fluoride. Platinum is a stable element Word Platinum comes from Spanish word Platina, which means little silver. Standard: BP/USP/EP The purity is equal or greater than 99%. With only four d-electrons, it is paramagnetic with a triplet ground state. Other data available: Vibrational and/or electronic energy levels. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health The compound is a unique example of platinum in the 6+ oxidation state. The results for the platinum compound agree well with the experimentally observed ligand field transition in optical spectra. Krogmann's salt -K 2 Pt(CN) 4 Br. However, while teaching at the University of British Columbia, Neil Bartlett discovered that the gas platinum hexafluoride (PtF6) was a powerful oxidizing agent that could oxidize oxygen gas (O2) to form dioxygenyl hexafluoroplatinate (O+ 2 ). [Phys. stated in. 3PtF Platinum hexafluoride is the chemical compound with the formula PtF6. (music) A single or album that has achieved platinum sales, i.e. Gravimetric and tensimetric evidence indicate that the initial product of the Cl/sub 2/ plus IrF/sub 6/ reaction is a solid of composition Cl/sub 2/IrF/sub 6/. The Preparation and Some Properties of Platinum Hexafluoride, Comment on 'Ground state of octahedral platinum hexafluoride', https://doi.org/10.1103/PHYSREVA.79.056501, Reply to 'Comment on 'Ground state of octahedral platinum hexafluoride'', https://doi.org/10.1103/PHYSREVA.79.056502, Oxidizing behavior of some platinum metal fluorides. Bartlett had recently been doing some work with platinum hexafluoride, a chemical that's such a strong oxidizer that it can oxidize oxygen. In 1962, Neil Bartlett used platinum hexafluoride to form a compound between xenon, platinum, and fluorine - xenon hexafluoroplatinate, Xe [PtF 6 ]. Platinum hexafluoride (English) quotation. The Pt-F bond lengths are 185 picometers. Sitelinks. 73, 35 (2001)] and also with a well known result concerning magnetic properties, NMR, and Jahn-Teller effect in the systems possessing even number of d electrons. Microsoft Academic ID. Platinum hexafluoride is the chemical compound with the formula Pt F 6, and is one of seventeen known binary hexafluorides. All rights reserved. Die oxidierenden Eigenschaften der Hexafluoride von Elementen der dritten bergangsreihe sowie verwandter Verbindungen. platinum hexafluoride Chemical Properties,Uses,Production Physical Properties Dark-red octahedral crystals; volatile and unstable; density 3.83g/cm3; melts at 61.3C; vaporizes at 69.14C; reacts violently with water. PtO 2 and the less common PtO both decompose upon heating. Platinum. did not account for the influence of {sup 19}F and {sup 195}Pt nuclear magnetic moments and vibronic interactions on the wave function of PtF{sub 6} molecules. The discovery of this reaction in 1962 proved that noble gases form chemical compounds. All previously published nonrelativistic and scalar relativistic electronic structure calculations of platinum hexafluoride predict a paramagnetic distorted octahedral molecule with a triplet ground state. PtF6 is a strong fluorinating agent and one of the strongest oxidants . Platinum hexafluoride f s the least stable and most reactive of the known hexafluorides. Platinum hexafluoride was obtained from Ozark-Mahoning Company, Tulsa, Oklahoma. Current & Historical Data Worldwide. The material usually has a low level of radioactivity with the chemical hazard greatly exceeding the radiation hazard for all but highly enriched materials. iv. This reaction, discovered by Neil Bartlett in 1962, proved that the noble gases are not totally unreactive. Molecular formula: PtF 6 Elements: Fluorine (F) , Platinum (Pt) Molecular weight: 309.074 g/mol Molar volume: 80.698 cm/mol PtF6 is a strong fluorinating agent and one of the strongest oxidants . . [2] This route remains the method of choice.[1]. Platinum hexafluoride Periodic table shop Printable periodic table Platinum hexafluoride Pt compounds More compounds. Uses of Platinum. The liquid density is 3.826 g cc/sup -1/ at 64.3 deg . Finally, in 1962, British chemist Neil Bartlett, working at the University of British Columbia in Vancouver, Canada, succeeded in reacting Xenon with the compound platinum hexafluoride (PtF 6 . The discovery of this reaction in 1962 proved that noble gases form chemical compounds. CAS Registry Number: 7783-75-7. Other names Platinum hexafluoride. Substance Name: Platinum hexafluoride RN: 13693-05-5 InChIKey: IEAIZEZQDJZVMI-UHFFFAOYSA-H Molecular Formula F6-Pt Molecular Weight 309.068 All Links to Resources Names & Synonyms Registry Numbers Structure Descriptors Links to Resources NLM Resources (File Locators) PubChem Other Resources (Internet Locators) eChemPortal EINECS EPA ACToR Formula: F 6 Ir. Chlorine is included in Inorganic Chemicals industry, covered in our Commodity Price Benchmarks. 6 had been shown to react with oxygen to form [O2]+[PtF6], dioxygenyl hexafluoroplatinate. Platinum hexafluoride is the first simple hexavalent platinum compound that has been prepared. Platinum hexafluoride does not have many commercial applications. This can be attributed to the fact that Alvarez-Thon et al. It is shown that the comments of Gabuda and Kozlova [Phys. A calculated f H(g) value of -669.47 kJ mol-1, in very good agreement with the experimental data from the literature, was . Uses Platinum hexafluoride does not have many commercial applications. Platinum hexafluoride (PtF 6) is an extremely strong fluorinating agent. Cotton, G. Wilkinson, C.A. The preparation of platinum hexafluoride and its use as a fluorinating agent in a process for separating plutonium from fission products is presented. The heat of transition is 2140 cal mole/sup -1/ and the heat of fusion is 1080 cal mole/sup -1/. A 77, 034502 (2008)] are in conflict with earlier work of the present authors [JETP Lett. Element Facts 40%. Platinum tetrafluoride is the inorganic compound with the chemical formula PtF4. PtF6 can also be prepared by disproportionation of the pentafluoride (PtF5), with the tetrafluoride (PtF4) as a byproduct. The table shows element percentages for PtF6 (platinum hexafluoride). It is a dark-red volatile solid that forms a dark red gas. It is a dark-red volatile solid that forms a red gas. platinum (IV) oxide peroxide. The compound is a unique example of platinum in the +6 oxidation state. Aqua regia -HNO 3 +3HCl. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health Reaction with liquid water is violent forming HF, oxygen, lower fluorides of platinum, and other products. The platinum hexafluoride is then contacted with the plutonium containing mixture at room temperature to form plutonium hexafluoride which is more volatile than the fission products fluorides and therefore can be isolated by distillation. It is formed by reacting platinum hexafluoride with relatively uncationisable elements and compounds, for example with xenon to form "XePtF6" (actually a mixture of XeFPtF5, XeFPt2F11, and Xe2F3PtF6), known as xenon hexafluoroplatinate. Platinum;hexafluoride | F6Pt-6 - PubChem Apologies, we are having some trouble retrieving data from our servers. Platinum . Neon Uses i. It is also an important component of the oxygen cylinders used in deep-sea diving. platinum hexafluoride and method of fluorinating plutonium containing mixtures there-with. With only four d-electrons, it is paramagnetic with a triplet ground state. However, while teaching at the University of British Columbia, Neil Bartlett discovered that the gas platinum hexafluoride (PtF6) was a powerful oxidizing agent that could oxidize oxygen gas (O2) to form dioxygenyl hexafluoroplatinate (O+ 2 ). ELLA. Relativistic effects on the hexafluoride of E110 are discussed, and a . iii. It is formed by reacting platinum hexafluoride with relatively uncationisable elements and compounds, for example with xenon to form "XePtF As a supplier, we can provide high-quality products. It's the 13th most abundant element found in Earth's crust with a concentration of 950 ppm in the upper layers. With only four d-electrons, it is paramagnetic with a triplet ground state. It details the challenges faced when beginning a business and offers suggestions on how to overcome these obstacle. It has been proposed that the platinum fluoride forms a negatively charged polymeric network with xenon or xenon fluoride cations held in its instices. Platinum hexafluoride is a strong oxidizer capable of oxidizing oxygen. A hexafluoroplatinate is a chemical compound which contains the hexafluoroplatinate PtF 6 anion. Show this safety data sheet to the doctor in attendance. Platinum hexafluoride 100% (1/1) PtF 6 platinum (VI) fluoride It can be produced by the reaction of dioxygen with platinum hexafluoride. Except where otherwise noted, data are given for materials in their, Drews, T.; Supel, J.; Hagenbach, A.; Seppelt, K. "Solid State Molecular Structures of Transition Metal Hexafluorides", https://infogalactic.com/w/index.php?title=Platinum_hexafluoride&oldid=660541, Creative Commons Attribution-ShareAlike License. Platinum hexafluoride is a volatile and unstable dark-red octahedral crystalline compound. 1 reference. : 237-214- CAS no. publication date. 13693-05-5) SDS. 2F The compound is a unique example of platinum in the +6 oxidation state. 5, XeFPt Reaction with liquid water is violent forming HF, oxygen, lower fluorides of platinum, and other products. PtF 6 can also be prepared by disproportionation of the pentafluoride (PtF 5 ), with the tetrafluoride (PtF 4 ) as a byproduct. platinum hexafluoride pronunciation with translations, sentences, synonyms, meanings, antonyms, and more. References. Except where otherwise noted, data are given for materials in their, Drews, T.; Supel, J.; Hagenbach, A.; Seppelt, K. "Solid State Molecular Structures of Transition Metal Hexafluorides", https://en.wikipedia.org/w/index.php?title=Platinum_hexafluoride&oldid=1118573799, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License 3.0. Wikipedia (25 entries) edit. The use of PtF/sub 6/ as a fluorinating agent at room temperature to form BrF/sub 5/, NpF/sub 6/, and PuF/sub 6/ is described. Its fame derives from its ability, when in gaseous form and mixed with an excess of xenon, to form XePtF 6 (xenon hexafluoroplatinate). Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. In their original publication they also stated that qualitative electrostatic considerations suggest that the electronic 5d{sup 4} configuration remains spin paired as the ground state in the octahedral field00. Clearanc Platinum hexafluoride is the first simple hexavalent platinum compound that has been prepared. Murillo, and M. Bochmann, in. The material was further purified by low temperature distillation according to the procedure described.' The infrared spectrum8 and vapor pressure of the pure material agreed well with the published values. WikiMatrix. Identifiers CAS Number. Interestingly, it was a mustard yellow solid compound. PtF 6 is a strong oxidant and a strong fluorinating agent that is . Vibrational spectroscopic and other evidence indicates that this solid yields a sequence of products, of which Cl/sub 3//sup +/IrF/sub 6//sup -/, Cl/sub 3//sup +/Ir/sub 2/F/sub 11//sup -/ and Ir/sub 4/F/sub 20/ have been identified, the last being the ultimate solid product of the room temperature decomposition of the adduct. Health Issues. CAS no. If inhaled. With only four d-electrons, it is paramagnetic with a triplet ground state. Thank you. WebElements: THE periodic table on the WWW [www.webelements.com] With only four d-electrons, it is paramagnetic with a triplet ground state. ( wikipedia platinum ) The metallic chemical element with atomic number 78 and symbol Pt. dark brick red, rhomb solid; strong oxidizing agent; there are also PtF4, 13455-15-7, and PtF5, 13782-84-8 [KIR82], Copyright 2022 ChemicalBook. Platinum(IV) oxide, PtO 2, also known as Adams' catalyst, is a black powder that is soluble in KOH solutions and concentrated acids. 3. The formula was established by chemical analyses and vapor density. PtF6 is a strong oxidant and a strong fluorinating agent. Platinum hexafluoride is dangerously corrosive. On Tuesday May 23rd 2006 the American Chemical Society and the Canadian Society for Chemistry recognized the work of Professor Neil Bartlett as an International Historic Chemical Landmark. Platinum was discovered by Julius Scaliger in 1735. A whitish grey colour, like that of the metal. Chlorine Prices. . Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. Platinum Hexafluoride . According to the invention, platinum is reacted with fluorine gas at from 900 to 1100 deg C to form platinum hexafluoride. Xenon hexafluoroplatinate. Platinum Hexafluoride - Other Hexafluoride Compounds Other Hexafluoride Compounds The neutral hexafluorides of other elements are also volatile. Copyright 1993-2022 Mark Winter [ The University of Sheffield and WebElements Ltd, UK]. Darmstadtium hexafluoride (DsF 6) is predicted to have very similar properties to its lighter homologue platinum hexafluoride (PtF 6), having very similar electronic structures and ionization potentials. [Xe complexes with Pt, Pd fluorides; Chlorine-2 oxidation by transition metal hexafluorides], PLATINUM HEXAFLUORIDE AND METHOD OF FLUORINATING PLUTONIUM CONTAINING MIXTURES THERE-WITH. PtF6 is octahedral in both the solid state and in the gaseous state. Notes. 0 references . However, four-component Dirac molecular Hartree . Difficult (1 votes) The compound is a unique example of platinum in the +6 oxidation state. The heat of vaporization at the boiling point is 7060 cal mole/sup -1/. The mineralogy of Platinum Localities with greatest number of different Platinum mineral species map should go here 7 6 4 + 5000 km 3000 mi Leaflet | Localities mindat.org, Base map OpenStreetMap Spotted a mistake/omission? Previous to the experiment with xenon, had been shown to react with oxygen to form [O 2 ] + [PtF 6 ] , dioxygenyl hexafluoroplatinate. A preparation of "XePtF 6 " in HF solution results in a solid which has been characterized as a [PtF 5-] n polymeric network associated with XeF +. Formula: PtF 6 Hill system formula: F 6 Pt 1 CAS registry number: [13693-05-5] Formula weight: 309.068 Class: fluoride Colour: dark red Appearance: crystalline solid Melting point: 61.3C Boiling point: 69C Density: 4000 kg m -3 A Xe:PtF/sub 6/ material of approximately 1:1 stoichiometry has been prepared and compared with XePdF/sub 6/(XeF/sub 2/.PdF/sub 4/). ", Platinum tetrachloride pentahydrate: PtCl, Potassium trichloro(ammine)platinate: K[PtCl, Disodium hexachloroplatinate hexahydrate: Na, Potassium trichloro(ethene)platinate: K[PtCl, Chemical Rubber Company handbook of chemistry and physics, F.A. Xenon hexafluoroplatinate is the description of the product obtained from the combination of platinum hexafluoride and xenon in an experiment that proved the chemical reactivity of the noble gas es. The required PtF5 can be obtained by fluorinating PtCl2: Platinum hexafluoride can gain an electron to form the hexafluoroplatinate anion, PtF6. The four-component spin-free method also predicts a distorted octahedral molecule with longest axial Pt-F bond due to the Jahn-Teller effect. The hexafluoride is a very powerful oxidizing agent reacting violently with most oxidizable substances. Dark-red octahedral crystals; volatile and unstable; density 3.83g/cm3; melts at 61.3C; vaporizes at 69.14C; reacts violently with water. : 13693-05-5 (English) Freebase ID /m/07j39m. Inhalation of its vapors or skin contact causes serious injury. over 1 million or 2 million. - These pages are a work in progress, so please send all comments/corrections to jolyon@mindat.org. 11, and Xe Fluoride compounds also have significant uses in synthetic organic chemistry. Previous to the experiment with xenon, PtF The hexafluoride decomposes on heating; also decomposed by UV radiation to lower fluorides; and reacts with the inert gas xenon, forming a solid product, Xe(PtF6). Platinum(II,IV) oxide, Pt 3 O 4, is formed in the following reaction: Platinum hexafluoride is the chemical compound with the formula Pt F 6. Molecular formula: PtF 6 Elements: Fluorine (F) , Platinum (Pt) Molecular weight: 309.074 g/mol Molar volume: 80.698 cm/mol CAS Registry Number (CAS RN): 13693-05-5 Volume 18, Issue 3, March 1986, Pages 235-240. PtF6 is octahedral in both the solid state and in the gaseous state. platinum hexafluoride (CAS No. Select Speaker Voice. See more Darmstadtium. [2] This route remains the method of choice.[1]. It is a dark-red volatile solid that forms a red gas. Rev. 73, 35 (2001)], where they stated that there is no indication of the structural distortions in PtF{sub 6}. Boiling Point (BP), Platinum hexafluoride changes its state from liquid to gas at 69.14C (156.452F or 342.29K) Platinum hexafluoride is a volatile and unstable dark-red octahedral crystalline compound. Platinum hexafluoride is the chemical compound with the formula Pt F 6, and is one of seventeen known binary hexafluorides. According to the Centers for Disease Control and Prevention, short-term exposure to platinum salts may cause irritation of the eyes, nose, and throat, and long-term exposure may cause both respiratory and skin allergies. A modern synthesis involves thermal decomposition of platinum hexafluoride. The formula was established by chemical analyses and vapor density. Uranium hexafluoride, upon exposure to moisture in air will release hydrogen fluoride which is a poisonous and corrosive gas as well as uranyl oxyfluoride which is a nephrotoxin. The chart below shows the calculated isotope pattern for the formula PtF6 with the most intense ion set to 100%. Platinum Hexafluoride Market 2022 to 2028 Latest Industry Trends, Overview of Segments, New Technology and Growth Analysis - MarketWatch Home Press Release Platinum Hexafluoride Market 2022 to. Platinum hexafluoride is the chemical compound with the formula PtF6, and is one of seventeen known binary hexafluorides. 2. platinum hexafluoride. Fluid helium is frequently used to cool superconducting magnets in atomic magnetic resonance spectrometers. Patent 2,709,186). A solid transition occurs at 3.0 deg , 32.5 mm pressure and the fusion point is 61.3-, 586 mm. Rev. Darmstadtium is a synthetic chemical element with symbol Ds and atomic number 110. It is a dark-red volatile solid that forms a red gas. PtF 6 is a strong oxidant and a strong fluorinating agent. Platinum Fluoride is a water insoluble Platinum source for use in oxygen-sensitive applications, such as metal production. -Platinum fluoride: 13693-05-5 : none : 100%: 4. Platinum hexafluoride. 6), known as xenon hexafluoroplatinate. A preparation of "XePtF 6 " in HF solution results in a solid which has been characterized as a [PtF 5] polymeric network associated with XeF +. The thermal decomposition of XeFPtF/sub 6/ or XePd/sub 2/F/sub 10/ yields highly pure XeF/sub 4/. The density of the low temperature solid varies between 6.0-5.0 g cc/sup -1/ in the range 77-254 deg K. The vapor and liquid are red in color and the solids appear black. How to say platinum hexafluoride in English? : 13693-05-5 Mol. Rate the pronunciation struggling of Platinum Hexafluoride. 28 October 2013. A weight loss-versus-time curve indicated the presence of 4:1, 3:1 and 2:1 XeF/sub 2//PdF/sub 4/ complexes. All rights reserved. Commodity. This reaction takes place at a temperature of 25-60C, in the atmosphere sulfur hexafluoride. Platinum hexafluoride Regulatory process names 3 IUPAC names 1 Other identifiers 1 EC / List no. New!! In the present work, a computational thermochemistry study (semiempirical, PM6 method) for platinum hexafluoride (PtF 6) is performed.The gas-phase formation enthalpy ( f H) and electron affinity are calculated and the results compared with the experimental data. The interaction of chlorine with the third-series transition metal hexafluorides has been investigated. Platinum hexafluoride is the chemical compound with the formula PtF6, and is one of seventeen known binary hexafluorides. Platinum is used largely for vehicle emissions control devices. + 27.7758; cubic solid, log P (mm) = 2528.7/ T -4.080 log T + 20.6280; liquid, log P (mm) = --5685.8/T - 27.485 log T + boiling point of the known hexafiuorides. The vapor pressure equations are: orthorhombic solid, log P (mnm) = --3147.6/T - 6.09 log T. It is shown that the principal results of a recent work by Alvarez-Thon et al. The current OSHA standard is 2 micrograms per cubic meter of air averaged over an 8-hour work shift. The oxidation number of platinum in platinum trioxide is 4. With only four d-electrons, it is paramagnetic with a triplet ground state. osti.gov patent: platinum hexafluoride and method of fluorinating plutonium containing mixtures there-with. Reaction: The hexafluoride is a very powerful oxidizing agent reacting violently with most oxidizable substances. This page was last edited on 27 October 2022, at 19:27. It's an extremely rare metal with an abundance in Earth's crust of about a millionth of 1 percent. Formula: F 6 Pt; Molecular weight: 309.074; CAS Registry Number: 13693-05-5; Information on this page: Gas phase ion energetics data; References; Notes; Options: Switch to calorie-based units You can reference the WebElements periodic table as follows:"WebElements, https://www.webelements.com, accessed December 2022. Platinum hexafluoride forms compounds with molecular oxygen and xenon, [O2+][PtF6 -] and XePtF6 , respectively. full record; other . Find another reaction Thermodynamic properties of substances The solubility of the substances Periodic table of elements Picture of reaction: Platinum hexafluoride is the chemical compound with the formula Pt F 6. Intratec provides Chlorine pricing data, covering current prices and 15 years of historical data. PtF6 is a strong fluorinating agent and one of the strongest oxidants, capable of oxidising xenon and O2. This was achieved by burning a platinum wire in a fluorine atmosphere adjacent to a cold surface with yields of up to 70%. 4 /5. As a reminder, oxidizing agents are chemicals that can strip electrons away from other atoms. The compound is a unique example of platinum in the +6 oxidation state. Definitions of Platinum hexafluoride, synonyms, antonyms, derivatives of Platinum hexafluoride, analogical dictionary of Platinum hexafluoride (English) Sodium hexachloropl -Na 2 PtCl 6. Potassium tetrachloropla -K 2 PtCl 4. Professor Bartlett, working at UBC, demonstrated the first reaction of a noble gas by combining xenon with platinum hexafluoride. It is a dark-red volatile solid that forms a red gas. 1. BIOGRAPHY Enthalpy of formation of platinum hexafluoride Consult a physician. The following are some synonyms of platinum hexafluoride: The oxidation number of platinum in platinum hexafluoride is 6. [1], PtF6 was first prepared by reaction of fluorine with platinum metal. Platinum hexafluoride is the chemical compound with the formula PtF6, and is one of seventeen known binary hexafluorides. It reacts with molecular oxygen to produce O2+PtF6 The compound attacks glass at ordinary temperatures. Freebase Data Dumps. or PtF/sub 5/) or palladium fluorides (Pd/sub 2/F/sub 6/ or PdF/sub 4/) provides for the conversion of XeF/sub 2/ to XeF/sub 4/. With only four d-electrons, it is paramagnetic with a triplet ground state. It gives a synopsis of the market, outlining its definition, uses, advancements, and production techniques. Also, it can react explosively with a number of substances. The new compounds XeF/sub 2/.PdF/sub 4/ and XeF/sub 2/.2PdF/sub 4/(XePd/sub 2/F/sub 10/) were produced by interaction of XeF/sub 2/ with either PdF/sub 4/ or Pd/sub 2/F/sub 6/. Xenon react with platinum hexafluoride to produce xenon hexafluoroplatinate (V). The first known example of a compound of a noble gas was made by Neil Bartlet using this element and platinum hexafluoride . 6. Noun. The compound is a unique example of platinum in the +6 oxidation state. Previous to the experiment with xenon, PtF6 had been shown to react with oxygen to form [O2]+[PtF6], dioxygenyl hexafluoroplatinate. In a preferred embodiment of the invention, embracing the preferred conditions given, anhydrous sulfur tetrafluoride mixed with enough chlorine to react with all elemental sulfur produced is continuously passed at 9001500 C. and ambient pressure through a clean, inert reactor. This univalent poisonous gaseous halogen element of the periodic table forms a vast number of compounds with the other chemical elements, even with the noble gases krypton, xenon, and radon. The compound is a unique example of platinum in the +6 oxidation state. 2F Angewandte Chemie 1968 , 80 (12) , 453-460. The previously known compounds Xe/sub 2/F/sub 3//sup +/PtF/sub 6//sup -/, XeF/sup +/PtF/sub 6//sup -/ and XeF/sub 2/.2PtF/sub 4/(XePt/sub 2/F/sub 10/) were prepared by the interaction of XeF/sub 2/ with PtF/sub 4/. This was achieved by burning a platinum wire in a fluorine atmosphere adjacent to a cold surface with yields of up to 70%. CAS No: 13693-05-5; . The compound is a unique example of platinum in the +6 oxidation state. 2781065020. These include osmium, iridium, rhodium, ruthenium, rhenium, tungsten, technetium, and uranium. Since then, many compounds of xenon have been formed, along with some compounds of krypton, and with much difficulty, argon fluorohydride - HArF. It is used as a strong oxidizing agent and can oxidize oxygen from the air. platinum hexafluoride Min.Order: 10 Gram FOB Price: USD $ 0.0-0.0/Gram High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Platinum hexafluoride forms compounds with molecular oxygen and xenon, [O2+][PtF6 ] and XePtF6 , respectively. Neil Bartlett at the University of British Columbia formulated the product as "Xe + [PtF 6] ", although subsequent work suggests that Bartlett's product was probably a . The super-oxidising compound was platinum hexafluoride, a yellow-brown solid substance recently discovered by Bernard Weinstock and his colleagues at the Argonne National Laboratory . Formula: Key datasets Brief Profile REACH registered substance factsheets Inventory Biocidal active substance factsheets Regulatory Obligations Regulatory context Melting point: 25C (decomposes) Boiling point: Density: The following are some synonyms of platinum trioxide: platinum trioxide. With only four d-electrons, it is paramagnetic with a triplet ground state. It is also used as a cooling gas in gas-cooled atomic reactors as well as a stream gas in gas-fluid chromatography. Chloroplatinic acid -H 2 PtCl 6. In extremely low concentrations (ppm), fluoride compounds are used in health applications. Molecular weight: 306.207. 6" (actually a mixture of XeFPtF Platinum hexafluoride | F6Pt-2 - PubChem Apologies, we are having some trouble retrieving data from our servers. A new chlorine fluoride generated in the room temperature decomposition of Cl/sub 2/IrF/sub 6/ has been tentatively formulated as Cl/sub 3/F from infrared evidence. Pronunciation of platinum hexafluoride. This market research report India Sulfur Hexafluoride monitors any fresh developments and enhancements. It is a dark-red volatile solid that forms a red gas. First-aid measures 4.1 Description of necessary first-aid measures General advice. Known since ancient times, this transition metal has strong anti-corrosive properties and makes for an excellent conductor of electricity. The element Platinum is extremely rare and is hard to find. The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following. platinum oxide. Platinum_hexafluoride; dbr:Tetrahedral_molecular_geometry; dbc:Fluorides; dbr:Bromine_trifluoride; dbc:Platinum(IV)_compounds; dbr:Selenium_tetrafluoride; However, it is found mixed in with some other metals such as gold, nickel, and copper. Pronunciation of platinum hexafluoride with 1 audio pronunciation, 13 translations and more for platinum hexafluoride. The Pt-F bond lengths are 185 picometers. The compound XePd/sub 2/F/sub 10/ is a close structural relative of XePt/sub 2/F/sub 10/, and spectroscopic evidence suggests that both are salts of XeF/sup +/ and a polymeric (M/sub 2/F/sub 9/)/sub x//sup x-/ ion. It is a dark-red volatile solid that forms a red gas. It is a dark-red volatile solid that forms a red gas. Xenon hexafluoroplatinate From Wikipedia, the free encyclopedia Xenon hexafluoroplatinate is the product of the reaction of platinum hexafluoride and xenon, in an experiment that proved the chemical reactivity of the noble gases. The molecule does not rotate freely in any of the condensed phases. In the solid state, the compound features platinum(IV) in octahedral coordination geometry. A 79, 056501 (2009)] are in conflict with their earlier work [S. P. Gabuda et al., JETP Lett. Information on this page: Gas phase ion energetics data. It is also expected to have the same octahedral molecular geometry as PtF 6. 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